Anomalously large interface charge in polarity-switchable photovoltaic devices: an indication of mobile ions in organic-inorganic halide perovskites

作者:Zhao Yong; Liang Chunjun*; Zhang Huimin; Li Dan; Tian Ding; Li Guobao; Jing Xiping; Zhang Wenguan; Xiao Weikang; Liu Qian; Zhang Fujun; He Zhiqun
来源:Energy & Environmental Science, 2015, 8(4): 1256-1260.
DOI:10.1039/c4ee04064c

摘要

It is proved that a large amount of mobile ions exist in organic-inorganic halide perovskites. The accumulated ions at the interface change the band bending of the semiconductor, leading to polarity-switchable photovoltaic devices. The interface charge significantly influences the function and performance of perovskite devices. The discovery of the interface charge has important implications for current-voltage hysteresis in perovskite solar cells.