Multi-sites for Mn2+ in barium beta-alumina

作者:Li Feng*; He Yuyang; Zhang Li
来源:Journal of Luminescence, 2011, 131(5): 975-977.
DOI:10.1016/j.jlumin.2011.01.005

摘要

Barium beta-alumina (Ba0.75Al11O17.25) doped with different contents of Mn2+ was prepared by conventional solid state method and analyzed by photoluminescence (PL) spectroscopy. It is found that there are multi-bands that could be attributed to Mn2+ in the PL spectra in addition to the 515 nm band ascribed to Mn2+ in Al(2). By analyzing the crystallographic structure of barium beta-alumina, it is concluded that the other sites for Mn2+ can be associated with the interstitial Al(5) and Ba sites in the mirror layers.

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