A highly efficient non-heme manganese complex in oxygenation reactions

作者:Nehru Kasi; Kim Soo Jeong; Kim In Young; Seo Mi Sook; Kim Youngmee; Kim Sung Jin; Kim Jinheung; Nam Wonwoo*
来源:Chemical Communications, 2007, (44): 4623-4625.
DOI:10.1039/b708976g

摘要

A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.

  • 出版日期2007