科研之友
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摘要
The analytic correlation rule of Gershtein and Krivchenkov between states in the united atom and separated atom limits for one-electron diatomic molecule is extended to diatomic molecules with more than one electron for diabatic screened molecular orbitals, which are solutions of the Hartree-like Schrodinger equation that is separable in prolate spheroidal coordinates. The rule is interpreted with the WKB method.
- 出版日期2018-6
