Substrate-dependent deposition behavior of graphite particles dry-sprayed at room temperature using a nano-particle deposition system

作者：Al Nasim Mohammad Nur E Alam; Chun Doo Man^*

来源：Surface and Coatings Technology, 2017, 309: 172-178.

DOI：10.1016/j.surfcoat.2016.11.062

• Graphite deposition
• Nanoparticle deposition system (NPDS)
• Dry spraying
• Cold spraying
• Aerosol deposition method (ADM)
• Substrate effect

This work demonstrates the effect of the substrate upon the deposition of graphite microparticles during thin film preparation at room temperature using a nanoparticle deposition system (NPDS). NPDS is a dry spray deposition method, whereby various metal and ceramic powders can be deposited at room temperature without the use of any binders. Graphite powder was deposited on various substrates of different hardness, namely polystyrene, copper, glass, and sapphire, and the substrate-dependent deposition behaviors were investigated. For the soft polystyrene substrate, graphite particles fragmented into small pieces during deposition, but retained the original graphite crystal structure. For the copper substrate, which is of intermediate hardness, some areas of the deposited film showed fragmented particles that had undergone interlayer separation to yield few-layer graphene flakes, but in other areas of the film a fragmented graphite structure was observed, of particles that did not undergo interlayer separation. In contrast, intense fragmentation and interlayer separation of microscale graphite particles to form small and few-layer graphene flake structures were observed on the hardest substrates, glass and sapphire. The degree of fragmentation and interlayer separation of the microscale graphite particles were substrate-dependent: these phenomena increased as the hardness of the substrate was increased.

• 出版日期2017-1-15