A novel bithiazole-containing polymeric complex with soft ferromagnetism

作者：Jiang LM; Sun WL^*

来源：Polymers for Advanced Technologies, 2005, 16(8): 646-649.

DOI：10.1002/pat.622

• bithiazole
• soft ferrornagnetism
• synthesis
• FT-IR
• X-ray

A novel polymer resulting from the polycondensation of 2,2'-diamino-4,4'-bithiazole (DABT) with 5,5'-methylene-bis-salicylaidehyde (MBSA) and its ferric complex are described. Analyses of Fourier transform infrared (FT-IR) and X-ray photoelectron spectroscopy (XPS) revealed that both bithiazole residue and Schiff-base moiety acted as coordination sites for Fe 31 ions in the polymeric matrix. The magnetic behavior of the complex was studied as a function of magnetic field strength (0-60 kOe) at 25 K and as a function of temperature (5-300 K) at a magnetic field strength of 30 kOe. The hysteretic loop was measured at 5 K for the complex showing coercivity (H-c) of 20 Oe and remnant magnetization (M-r) of 0.002 emu/g, which is much lower than those of bithiazole-based polymeric complexes previously reported. The results indicated that the present complex is of the typical characteristics of a soft ferromagnet.

• 出版日期2005-8
• 单位浙江大学