Achiral aromatic solvent-induced assembly of 3-D homochiral porous 3d-4f heterometallic-organic frameworks based on isonicotinic acid

作者：Jin, Hong-Guang; Hong, Xu-Jia; Tan, Hao-Chong; Wei, Qin; Lin, Xiao-Ming; Cai, Yue-Peng^*

来源：CrystEngComm, 2017, 19(40): 5956-5959.

DOI：10.1039/c7ce01580a

• HETEROGENEOUS ASYMMETRIC CATALYSIS
• CHIRAL-SYMMETRY-BREAKING
• SPONTANEOUS RESOLUTION
• COORDINATION POLYMER
• ENANTIOSELECTIVE SEPARATION
• MICROPOROUS FRAMEWORK
• IONOTHERMAL SYNTHESIS
• 3D ARCHITECTURES
• BUILDING-BLOCKS
• SINGLE-CRYSTAL

Via induction of achiral aromatic solvents, two 3-D monochiral 3d–4f MOFs (<bold>1</bold> and <bold>2</bold>) from the ligand HIN without any chiral auxiliary are uncommonly constructed. And the results show homochirality of <bold>1</bold> and <bold>2</bold> are enantiopurity rather than enantiomeric excess.

• 出版日期2017-10-28