Hydrogenation of Phenol over Pt/CNTs: The Effects of Pt Loading and Reaction Solvents

作者：Li, Feng; Cao, Bo; Zhu, Wenxi; Song, Hua; Wang, Keliang; Li, Cuiqin^*

来源：Catalysts, 2017, 7(5): 145.

DOI：10.3390/catal7050145

• Pt/CNTs
• phenol
• hydrogenation
• loading method
• reaction solvent

Carbon nanotubes (CNTs)-supported Pt nanoparticles were prepared with selective deposition of Pt nanoparticles inside and outside CNTs (Pt-in/CNTs and Pt-out/CNTs). The effects of Pt loading and reaction solvents on phenol hydrogenation were investigated. The Pt nanoparticles in Pt-in/CNTs versus Pt-out/CNTs are smaller and better dispersed. The catalytic activity and reuse stability toward phenol hydrogenation both improved markedly. The dichloromethane-water mixture as the reaction solvent, compared with either pure medium, decreased the catalytic activity toward phenol hydrogenation and selectivity of cyclohexanone over Pt-in/CNTs, but significantly improved the catalytic activity toward phenol hydrogenation and selectivity of cyclohexanone over Pt-out/CNTs.

• 出版日期2017-5
• 单位东北石油大学