An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism

作者：Abe Masaaki^*; Futagawa Hiroki; Ono Toshikazu; Yamada Teppei; Kimizuka Nobuo; Hisaeda Yoshio

来源：Inorganic Chemistry, 2015, 54(23): 11061-11063.

DOI：10.1021/acs.inorgchem.5b02129

Oxidative electropolymeization of an axially bound, bithiophene pyridine complex of ruthenium(III) porphycene [Ru(TPrPc) (btp)(2)]PF6 (1) gives a submicrometer-thick, polymeric film on an ITO electrode with a crystalline morphology. The polymeric film, the first example of axially linked multimetalloporphycene coordination arrays, exhibits highly stable and reproducible electrochromic response with high electrochromic efficiency upon electrochemical control over the metal-centered electron transfer process (Ru-II/Ru-III).

• 出版日期2015-12-7