A variable temperature NMR analysis and resonance assignment of the Grubbs second generation catalyst

作者：Swart Marthinus Rudi; Twigge Linette^*; Marais Charlene; Bezuidenhoudt Barend Christiaan Buurman

来源：Polyhedron, 2018, 152: 31-36.

DOI：10.1016/j.poly.2018.06.024

• Grubbs second generation catalyst
• NMR
• H-1
• C-13
• 2D techniques

The Grubbs second generation catalyst [RuCl2(PCy3)(H(2)IMes)CHPh] was analysed in solution in order to identify and assign all of the H-1 and C-13 NMR resonances. This was achieved through utilizing various 2D NMR techniques and by acquiring spectra at a range of different temperatures (-40 to 60 degrees C). These assignments will aid researchers in future NMR studies of catalytic systems that employ the Grubbs catalyst by eliminating the resonances belonging to the catalyst and thus enabling the identification of any intermediates and/or new catalytic species. Restricted conformations and pi-stacking arrangement within the catalyst was also confirmed during this study.

• 出版日期2018-9-15