摘要
In-situ high-energy X-ray diffraction was used for tracing the structural transitions in Ni(2)MnGa and Ni(47)Mn(25)Ga(22)Co(6) nanoparticles that were prepared by a ball-milling and subsequent annealing process. A decrease in martensitic transformation temperature was evidenced in all annealed nanoparticles. It was found that a three-layered modulated structure, usually observed as a metastable premartensitic phase in coarse-grained alloys, becomes a stable phase in the annealed Ni(2)MnGa nanoparticles up to 4 K.
- 出版日期2008-2
- 单位东北大学