Preparation and Stabilization of Ag Nanoparticles in 1-Amino-4-methylpiperazine

作者:Park Heon Soo; Shin Ueon Sang; Kim Hae Won; Gong Myoung Seon*
来源:Bulletin of the Korean Chemical Society, 2011, 32(1): 273-276.
DOI:10.5012/bkcs.2011.32.1.273

摘要

Uniform Ag nanoparticles (< 10 nm) were effectively prepared in 1-amino-4-methylpiperazine as a solvent with multiple functions including reduction and stabilization. An Ag-complex such as Ag-2(ehac)(2)(eha)(2)(ehac = 2-ethylhexylammonium carbamate; eha = 2-ethylhexylamine) was used as an Ag-precursor, whereas the usage of a salt such as AgNO3 showed the formation of Ag nanoparticles in larger and irregular size (30 - 500 nm). The Ag nanoparticles (< 10 nm) prepared by using the Ag-complex could also be effectively stabilized by 1-amino-4-methylpiperazine. Transmission electron micrographs confirmed that the Ag particles were spherical and in the nanometer size.

  • 出版日期2011-1-20