A solid glycine-based precursor for the preparation of La2CuO4 by combustion method

作者：Komova O V^*; Mukha S A; Netskina O V; Odegova G V; Pochtar A A; Ishchenko A V; Simagina V I

来源：Ceramics International, 2015, 41(1): 1869-1878.

DOI：10.1016/j.ceramint.2014.09.139

• Organometallic precursor
• Volume combustion synthesis
• Self propagating high-temperature synthesis
• La2CuO4

A complex solid-state organometallic La(2)CuGlyNH(4)NO(3) precursor of a layered La2CuO4 perovskite has been synthesized and studied. It has been shown that such a precursor is capable of ignition and burning to produce oxide phases. The combustion process can occur in two regimes: the volume combustion synthesis (VCS) and the self-propagating high-temperature synthesis (SHS). Phase composition of the combustion products has been studied by physicochemical methods (infrared spectroscopy, X-ray diffraction, transmission electron microscopy). It was found that uncalcined as-synthesized product from the SHS regime is a well-defined crystalline La2CuO4 phase.

• 出版日期2015-1