A novel three dimensional 3d-4f heterometallic coordination framework with 2, 2 '-bipyridine-3-carboxylate and oxalate ligands

作者：Tang, Yun-Zhi^*; Wen, He-Rui; Cao, Zan; Wang, Xiao-Wei; Huang, Shuai; Yu, Chang-Lin

来源：Inorganic Chemistry Communications, 2010, 13(8): 924-928.

DOI：10.1016/j.inoche.2010.04.027

• Heterometallic polymer
• Hydrothermal synthesis
• Neodymium complex
• Copper complex

The 3D heterometallic polymeric complex 1 {[Nd2Cu2(L)(2)(OXA)(4)center dot 2(2H(2)O)]center dot 2(3H(2)O)}(n) (HL = 2, 2'-bipyridine-3-carboxyic acid, OXA = oxalate) was obtained from hydrothermal reaction of Nd2O3, Cu(ClO4)(2), HL and oxalic acid in the presence of ethanol and water. X-ray single crystal diffraction investigation of the polymeric complexes {[Nd2Cu2(L)(2)(OXA)(4)center dot 2(2H(2)O)]center dot 2(3H(2)O)}(n) exhibits an interesting and novel topological structure.

• 出版日期2010-8
• 单位江西理工大学