Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis-Hillman reactions

作者：Garre Satish; Parker Erica; Ni Bukuo^*; Headley Allan D

来源：Organic and Biomolecular Chemistry, 2008, 6(17): 3041-3043.

DOI：10.1039/b808502a

Three novel chiral ionic liquids (CILs) containing two chiral centers in the side chain bonded to the 2-position of the imidazolium cation and different anions have been synthesized, characterized and used as chiral solvents for asymmetric Baylis-Hillman (BR) reactions; good yields and fair enantioselectivities were obtained.

• 出版日期2008-9-7