A saccharide-based crystalline sponge for hydrophilic guests

作者:Ning Guo Hong; Matsumura Kazuki; Inokuma Yasuhide; Fujita Makoto
来源:Chemical communications, 2016, 52(43): 7013-7015.
DOI:10.1039/c6cc03026b

摘要

A coordination network composed of a mannose-based organic ligand and a sodium ion, 'sugar sponge', was synthesized for the crystalline sponge analysis of hydrophilic compounds. Owing to multiple hydrogen-bonding interactions, hydrophilic guests are firmly trapped in the 1-dimensional channel. The sugar sponge was utilized to analyze the structures of flexible alcohol and absolute configurations of chiral epoxides.

  • 出版日期2016