Nickel-thiolate and iron-thiolate cyanocarbonyl complexes: Modeling the nickel and iron sites of [NiFe] hydrogenase

作者：Chiou Tzung Wen; Liaw Wen Feng^*

来源：Comptes Rendus Chimie, 2008, 11(8): 818-833.

DOI：10.1016/j.crci.2008.04.003

• nickel-thiolates
• iron-thiolate cyanocarbonyl
• hydrogenases
• model compound

During the past decade, structures and functions (catalytic mechanism) of [NiFe]/[Fe] hydrogenases have been established/proposed. Model compounds, various biophysical measurements and theoretical calculations have been lent to elucidate the structure and catalytic mechanism) of active sites of [NiFe]/[Fe] hydrogenases. In this manuscript, biominetic model compounds, including iron(II)-thiolate cyanocarbonyls, nickel(III)-thiolates and nickel(II)-thiolate complexes with pendant thiol, are presented.

• 出版日期2008-8
• 单位清华大学