Nickel catalytic graphitized porous carbon as electrode material for high performance supercapacitors

作者：Wang Keliang; Cao Yuhe; Wang Xiaomin; Kharel Parashu Ram; Gibbons William; Luo Bing; Gu Zhengrong; Fan Qihua; Metzger Lloyd

来源：Energy, 2016, 101: 9-15.

DOI：10.1016/j.energy.2016.01.059

• Nickel catalytic graphitized
• Nitrogen doped carbon
• Porous carbon
• Supercapacitor

Whey-protein-derived nitrogen-doped porous carbon has been prepared by preliminary carbonization at 400 degrees C and final KOH activation at 700 degrees C combined with catalytic graphitization. Physical characterization indicated that the nitrogen-doped activated electrode material had a large specific surface area (2536 m(2) g(-1)) and plenty of interconnected cavities, which greatly improved the performance of supercapacitors. Electrochemical measurements demonstrated that the as-prepared activated electrode material had exceptionally high capacitance of 248 F g(-1) at charge/discharge current density of 0.1 A g(-1). Moreover, the prepared supercapacitors exhibited ideal capacitive behavior with nearly no capacitance loss in 6 mol L-1 KOH at different charge/discharge current densities ranging from 0.1 to 5 A g(-1) after 1000 charge/discharge cycles. The derived energy density was 12.4 Wh kg(-1) at a power density of 495 W kg(-1) under operational conditions. These results suggested that the whey-protein-derived porous carbon is a promising supercapacitor electrode material.

• 出版日期2016-4-15