A multi-stimuli-responsive fluorescence switch based on E-Z isomerization of hydrazone

作者：Zheng, Hai-Rong; Niu, Li-Ya^*; Chen, Yu-Zhe; Wu, Li-Zhu; Tung, Chen-Ho; Yang, Qing-Zheng

来源：RSC Advances, 2016, 6(47): 41002-41006.

DOI：10.1039/c6ra01507g

• MOLECULAR LOGIC
• VISIBLE-LIGHT
• BODIPY DYES
• PH
• SYSTEMS
• SENSORS
• 2-ARYLHYDRAZONES
• GLUTATHIONE
• DERIVATIVES
• BEHAVIOR

We report a new strategy to construct fluorescence switches by taking advantage of the sE-Z isomerization of the hydrazone group. The switch, synthesized by linking pyridyl-2-aldehydehydrazone to a BODIPY fluorophore, was able to exist in three forms: E-BODIPY, Z-BODIPY and protonated BODIPY with different photophysical properties. Reversible ON/OFF fluorescence switching among them was realized by multiple stimuli such as irradiation and addition of acid/base.

• 出版日期2016
• 单位中国科学院大学; 中国科学院理化技术研究所; 北京师范大学