A simplified approach to predict performance degradation of a solid oxide fuel cell anode

作者：Khan Muhammad Zubair; Mehran Muhammad Taqi; Song Rak Hyun; Lee Jong Won; Lee Seung Bok; Lim Tak Hyoung

来源：Journal of Power Sources, 2018, 391: 94-105.

DOI：10.1016/j.jpowsour.2018.01.080

• Solid oxide fuel cell
• Anode
• Polarization resistance
• Particle coarsening
• Triple phase boundary
• Prediction model of lifetime

The agglomeration of nickel (Ni) particles in a Ni-cermet anode is a significant degradation phenomenon for solid oxide fuel cells (SOFCs). This work aims to predict the performance degradation of SOFCs due to Ni grain growth by using a simplified approach. Accelerated aging of Ni-scandia stabilized zirconia (SSZ) as an SOFC anode is carried out at 900 degrees C and subsequent microstructural evolution is investigated every 100 h up to 1000 h using scanning electron microscopy (SEM). The resulting morphological changes are quantified using a twodimensional image analysis technique that yields the particle size, phase proportion, and triple phase boundary (TPB) point distribution. The electrochemical properties of an anode-supported SOFC are characterized using electrochemical impedance spectroscopy (EIS). The changes of particle size and TPB length in the anode as a function of time are in excellent agreement with the power-law coarsening model. This model is further combined with an electrochemical model to predict the changes in the anode polarization resistance. The predicted polarization resistances are in good agreement with the experimentally obtained values. This model for prediction of anode lifetime provides deep insight into the time-dependent Ni agglomeration behavior and its impact on the electrochemical performance degradation of the SOFC anode.

• 出版日期2018-7-1