Ultrasonic-assisted surfactant-free synthesis of highly magnetized FeCo alloy nanocrystallite from ferric and cobalt salt

作者:Wei, Xian-Wen*; Wu, Kong-Lin; Zhu, Guo-Xing; Liu, Yuan-Jun; Shi, Wei; Li, Xiang-Zi; Rong, Lu-Lu; Chen, Le; Wu, Fang-Hui
来源:Journal of Alloys and Compounds, 2012, 539: 21-25.
DOI:10.1016/j.jallcom.2012.06.056

摘要

Crystalline FeCo alloys (Fe64Co36, Fe59Co41, and Fe37Co63,) nanoparticles in diameter of 5-12 nm were synthesized by reduction of FeCl3 and CoCl2 with hydrazine under ultrasonic wave, which is a simple, low-cost, surfactant-free route, and may stimulate technological interests. As-synthesized Fe59Co41 nanocrystallite shows excellent soft magnetic behavior with high saturation magnetization up to 216.2 emu/g that is comparable with that of bulk Fe and Fe60Co40 alloy, and could have applications in catalysis, biotechnology, and magnetic storage devices.