A new 1-D In-Sb-S chain based on the linkage of bow-like [Sb3S7] units and pseudosemicube [In2SbS4] clusters

作者：Liu; Xing

来源：Inorganic Chemistry Communications, 2011, 14(2): 437-439.

DOI：10.1016/j.inoche.2010.12.022

• Solvothermal synthesis
• Thioindates
• Thioantimonates
• Crystal structure

The new thioindate-thioantimonate [Co(dien)(2)](2)In2Sb4S11 (1, dien = diethylenetriamine) was prepared under solvothermal conditions and structurally characterized. 1 consists of 1-D inorganic [In2Sb4S114-](n) chains constructed by bow-like trimeric [Sb3S7] units and heterometallic pseudosemicube [In2SbS4] clusters, and [Co (dien)(2)](2+) cations as counterions.

• 出版日期2011-2
• 单位玉林师范学院