Acetylene Black Loaded on Graphene as a Cathode Material for Boosting the Discharging Performance of Li/SOCl2 Battery

作者：Wei, Jun-Hua; Gao, Xiao-Tian; Tan, Si-Ping; Wang, Fang; Zhu, Xiao-Dong^*; Yin, Ge-Ping^*

来源：International Journal of Electrochemical Science, 2017, 12(2): 898-905.

DOI：10.20964/2017.02.01

• Li/SOCl2 batteries
• Cathode
• Assembly
• Graphene
• Acetylene black

Lithium thionyl chloride (Li/SOCl2) battery is a promising primary battery owing to its highest theoretical working voltage (3.6 V), excellent output specific energy (up to 590 Wh/kg) and large working temperature interval. However, drawbacks such as insoluble product (LiCl) and non- fully dissolved sulfur deposited on the electrode will cause the failure of the full battery. Herein, we report a cathode material that can boost the discharging performance of Li/SOCl2 battery by facile assembly of acetylene black nanoparticles on graphene nanosheets. The resulting acetylene black/graphene hybrid exhibits an excellent discharging performance, delivering a capacity as high as 1706 mAh/g at a current density of 5 mA/cm(2).

• 出版日期2017-2
• 单位塔里木大学; 哈尔滨工业大学