Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels

作者:Gu Ja Min; Kim Wan Seok; Huh Seong*
来源:Dalton Transactions, 2011, 40(41): 10826-10829.
DOI:10.1039/c1dt11274k

摘要

Lewis basic DABCO-functionalized 3D-like metal-organic framework, Zn-MOF, catalyzes nitroaldol (Henry) reaction of 4-nitrobenzaldehyde with nitroalkanes in a size-dependent manner. Small nitroalkanes give rise to higher conversion than larger ones. This MOF-based heterogeneous catalyst is very robust and can be recycled several times without losing its activity.

  • 出版日期2011