科研之友
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摘要
A highly selective C-H silylation reaction of functionalized arenes and heteroarenes was developed using RuppertPrakash reagent (TMSCF3) activated by alkali metal fluoride. TMSCF3 is considered to play dual roles as a precursor of a mild base and also as a silicon electrophile. The silylation is compatible with sensitive functional groups such as halogen and nitro groups.
- 出版日期2015-2-20
