Magnetic Field Effect on the Hydronium Diffusivity at an Enzymatic Biofuel Cell Anode via Atomistic Analysis

作者：Chiu C P; Hong C W^*

来源：Journal of Fuel Cell Science and Technology, 2010, 7(2): 021003.

DOI：10.1115/1.3081427

• enzymatic biofuel cell
• molecular dynamics
• hydronium ions

This paper investigates how a constant magnetic field between the anode catalyst and the electrode surface affects the performance of an enzymatic biofuel cell. Molecular dynamics techniques were employed to observe the nanoscale proton transport phenomenon. The simulation model comprised a Au electrode, pyrroloquinoline quinine, flavin adenine dinucleotide, and glucose macromolecules with hydronium ions in aqueous solution. A constant magnetic field was applied parallel to the anode electrode surface in the simulation process. It is found that the magnetic field is able to enhance the hydronium mobility in the solution and the rate of the biochemical reaction increased. Simulation results show that the hydronium diffusivity increases from 3.80 x 10(-9) m(2)/s to a maximum 19.91 x 10(-9) m(2)/s at a glucose concentration of 27 mM and from 13.02 x 10(-9) m(2)/s to a maximum 36.44 x 10(-9) m(2)/s at a glucose concentration of 82 mM. [DOI: 10.1115/1.3081427]

• 出版日期2010-4
• 单位清华大学