A homochiral diamond framework constructed from Fe(III) and Mn(II) oxo-clusters supported by Sb(III) tartrate scaffolds

作者：Gao Qiang; Wang Xiqu; Jacobson Allan J^*

来源：Chemical Communications, 2012, 48(33): 3990-3992.

DOI：10.1039/c2cc18174f

A homochiral diamond framework was obtained by using a secondary building unit (SBU) comprising an oxo-cluster containing 4Fe(III) and 3Mn(II) ions supported by Sb3O tartrate scaffolds. A fully protonated tetratopic cation, tetrakis(4-pyridyloxymethylene)-methane (TPOM), acts as a template to arrange the clusters on a diamond lattice.

• 出版日期2012