Aggregation of 1-dodecyl-3-methylimidazolium nitrate in water and benzene studied by SANS and H-1 NMR

作者：Takamuku Toshiyuki^*; Shimomura Takuya; Sadakane Koichiro; Koga Mikiko; Seto Hideki

来源：Physical Chemistry Chemical Physics, 2012, 14(31): 11070-11080.

DOI：10.1039/c2cp40891k

Aggregation of imidazolium-based ionic liquid, C(12)mim(+)NO(3)(-), in both polar solvent of water and nonpolar solvent of benzene was elucidated by electrical conductivity, small-angle neutron scattering (SANS), and H-1 NMR measurements. The electrical conductivities of C(12)mim(+)NO(3)(-) -water solutions at 298 K as a function of ionic liquid concentration showed a break point at 8.4 mmol dm(-3) as a cmc. However, those of C(12)mim(+)NO(3)(-) -benzene solutions drastically increase in accordance with a cubic function of concentration, but without a break point. The SANS profiles of both aqueous and benzene solutions obviously differ from each other. The profiles of the aqueous solutions indicated the formation of polydisperse spherical micelles. Those of the benzene solutions revealed Ornstein-Zernike behavior. Thus, C(12)mim(+)NO(3)(-) forms clusters in the benzene solutions, but the shape of clusters is indefinite. On the basis of the H-1 NMR chemical shifts of the aqueous solutions, the effect of nitrate on the formation of micelles was discussed on a microscopic scale. Furthermore, the interactions among C(12)mim(+), NO3-, and benzene molecules in the benzene solutions were considered according to the H-1 NMR data.

• 出版日期2012