A palladium(II) complex of 4 '-(4-pyridyl)-2,2 ': 6 ',2 ''-terpyridine: Lattice control through an interplay of stacking and hydrogen bonding effects

作者：Beves Jonathon E; Constable Edwin C^*; Housecroft Catherine E; Neuburger Markus; Schaffner Silvia

来源：Inorganic Chemistry Communications, 2007, 10(10): 1185-1188.

DOI：10.1016/j.inoche.2007.07.005

• Palladium(II)
• x-ray
• 2,2 ': 6 ',2 ''-terpyridine
• hydrogen bonding

The complex [Pd(1)Cl]Cl where 1 = 4'-(4-pyridyl)-2,2':6',2 ''-terpyridine is reported. The single crystal structure of [Pd(1)Cl]Cl center dot 3H(2)O center dot DMF features rows of columns of [Pd(1)Cl](+) cations which are supported by Pd...Pd interactions (3.367(1) and 3.440(1) angstrom) and separated by hydrogen-bonded 4.8(2) nets of water molecules and Cl- ions.

• 出版日期2007-10