A trinuclear Zn-3(OAc)(4)-3,3 %26apos;-bis(aminoimino)-binaphthoxide complex for highly efficient catalytic asymmetric iodolactonization

作者：Arai Takayoshi^*; Sugiyama Noriyuki; Masu Hyuma; Kado Sayaka; Yabe Shinnosuke; Yamanaka Masahiro

来源：Chemical Communications, 2014, 50(61): 8287-8290.

DOI：10.1039/c4cc02415j

A 3,3%26apos;-bis(aminoimino)BINOL ligand was newly designed and synthesized for the formation of a trinuclear Zn complex upon reaction with Zn(0Ac)2. Using the harmony of the tri-zinc atoms, 1 mol% Zn3(0Ac)4-3,3%26apos;-bis(aminoimino)binaphthoxide catalyzed asymmetric iodolactonization in up to 99.9% ee.

• 出版日期2014-8-7