Hybrid polymer containing ferric oxides obtained using a redox polymer Part I. Synthesis and characterization

作者：Jacukowicz Sobala Irena; Ciechanowska Agnieszka; Kociolek Balawejder Elzbieta^*

来源：Polimery, 2014, 59(2): 129-133.

DOI：10.14314/polimery.2014.131

• hybrid polymers
• iron oxides
• redox polymers
• nanocomposites

A hybrid polymer containing hydrated iron oxide was obtained in a one-step redox process. Macroporous S/DVB copolymer containing N-chlorosulfonamide groups in Na+ form ([P]-SO2NClNa) was used as a macromolecular oxidant for Fe(II) ions which in the form of iron oxide were deposited within a polymer matrix. The final product ([P]-SO2NH2#5Fe(2)O(3)center dot 9H(2)O) contained 12 % Fe(III) in the form of ferrihydrite which presence was confirmed by FT-IR and Mossbauer spectroscopic studies. The deposition of iron oxide caused reduction in BET surface and porosity of the host material.

• 出版日期2014-2