Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent pi-pi and contact ion interactions

作者：Maher Tiffany R; Meyers John J Jr; Spaeth Andrew D; Lemley Krista R; Barybin Mikhail V^*

来源：Dalton Transactions, 2012, 41(26): 7845-7848.

DOI：10.1039/c2dt30488k

Three synthetic routes to the unusual supramolecular complex ([Cp2Co](2)[{(OC)(5)V}(2)(mu-1,4-CNC6Me4NC)])(infinity), which was crystallographically characterized, are presented. The dianion [{(OC)(5)V}(2)(mu-1,4-CNC6Me4NC)](2-) constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

• 出版日期2012