Ideal and non-ideal behaviour of {1-butyl-1-methylpyrrolydinium bis(trifluoromethylsulfonyl)imide plus gamma-butyrolactone} binary mixtures

作者：Vranes Milan; Tot Aleksandar; Papovic Snezana; Zec Nebojsa; Dozic Sanja; Gadzuric Slobodan^*

来源：Journal of Chemical Thermodynamics, 2015, 81: 66-76.

DOI：10.1016/j.jct.2014.10.002

• Pyrrolydinium ionic liquids
• gamma-Butyrolactone
• Volumetric properties
• Electrical conductivity
• Viscosity
• Ideal solutions

Density, electrical conductivity and viscosity of binary liquid mixtures of 1-butyl-1-methylpyrrolydinium bis(trifluoromethylsulfonyl) imide, [bmpyrr][NTf2], with c-butyrolactone (GBL) were measured at temperatures from (293.15 to 323.15) K and at atmospheric pressure over the whole composition range. Excess molar volumes have been calculated from the experimental densities and fitted with the Redlich-Kister polynomial equation. These values are positive over the whole range of ionic liquid mole fraction and at all temperatures. In the range between 0.55 and 0.6 [bmpyrr][NTf2] mole fraction, an ideal behaviour of the ionic liquid mixture with molecular solvent was observed for the first time. Other volumetric properties, such as isobaric thermal expansion coefficients, partial molar volumes and partial molar volumes at infinite dilution have been also calculated, in order to obtain information about interactions between GBL and selected ionic liquid. Positive values of these properties for both components also indicate weaker interactions between GBL and IL compared to the pure components. From the viscosity results, the Angell strength parameter was calculated and found to be 3.24 indicating that [bmpyrr][NTf2] is a "fragile" liquid. From the volumetric and transport properties obtained, formation of the [bmpyrr](+) micellar structures was also discussed. All the results are compared to those obtained for imidazolium-based ionic liquid with GBL.

• 出版日期2015-2