Preparation and properties of co-oligomers of 1-vinyl-1,2,4-triazole with N-vinyl-2-phenylpyrrole

作者:Ermakova T G*; Korzhova S A; Kuznetsova N P; Mazyar I V; Larina L I; Pozdnyakov A S; Scherbakova V S; Mikhaleva A I; Prozorova G F
来源:Russian Journal of General Chemistry, 2015, 85(2): 472-476.
DOI:10.1134/S107036321502019X

摘要

Novel water-soluble co-oligomers of 1-vinyl-1,2,4-triazole and N-vinyl-2-phenylpyrrole have been prepared by radical copolymerization. Copolymerization constants of the monomers and the parameters of cooligomers microstructure have been determined. 1-Vinyl-1,2,4-triazole is more reactive in the monomers pair. The prepared co-oligomers are thermally stable and reveal properties typical of paramagnetic organic semiconductors.

  • 出版日期2015-2