Phosphorescence in Bromobenzaldehyde Can Be Enhanced through Intramolecular Heavy Atom Effect

作者:Sarkar Sunandan; Hendrickson Heidi P; Lee Dongwook; DeVine Francis; Jung Jaehun; Geva Eitan; Kim Jinsang*; Dunietz Barry D*
来源:Journal of Physical Chemistry C, 2017, 121(7): 3771-3777.
DOI:10.1021/acs.jpcc.6b12027

摘要

A synthetic route to achieve high phosphorescence quantum yield in a purely organic material was achieved by doping a crystal containing heavy bromine atoms with a molecule that contains a triplet producing aromatic carbonyl group. The enhanced phosphorescence originated from intermolecular nonbonding interactions between the bromine and the carbonyl oxygen. In this study we employ a computational approach to design molecules containing both structural motifs, which exhibit enhanced phosphorescence through intramolecular nonbonding interactions between bromine and carbonyl groups.

  • 出版日期2017-2-23