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摘要
Twelve aldehydes and ketones were synthesized in 65%~92% yields by deoximations of oximes catalyzed with iodine in green solvent water under microwave-assisted condition. The structures of all products were confirmed by the corresponding nuclear magnetic resonance spectrum (1HNMR) and mass spectrum (MS). The effects of solvent, the amount of iodine, microwave power and reaction temperature on the reaction were considered. The optimized reaction conditions: n(oximes):n(iodine)=1:0.5, and water (1 mol/L for oximes), microwave power 300 W, reaction temperature 70℃, reaction time 35 min.
- 出版日期2016
