An Electron Dynamics Mechanism of Charge Separation in the Initial-Stage Dynamics of Photoinduced Water Splitting in XMnWater (X=OH, OCaH) and Electron-Proton Acceptors

作者：Yamamoto Kentaro; Takatsuka Kazuo^*

来源：ChemPhysChem, 2015, 16(12): 2534-2537.

DOI：10.1002/cphc.201500416

• electron transfer
• hydrogen transfer
• nonadiabatic transitions
• photochemistry
• water splitting

An electron dynamics mechanism of charge separation in the initial stage of excited-state reactions of the class of XMnOH(2)AXMnOHHA (X=OH or OCaH; A=N-methylformamidine, guanidine, imidazole, or ammonia cluster) is reported. The dynamic effect of calcium doping is also revealed. This study provides a novel factor to be considered in designing efficient systems for photoinduced water splitting.

• 出版日期2015-8-24