NADH coenzyme model compound as photocatalyst for the direct arylation of (hetero)arenes

作者:Feng, Yi-Si; Bu, Xiao-Song; Huang, Bei; Rong, Chun; Dai, Jian-Jun; Xu, Jun; Xu, Hua-Jian*
来源:Tetrahedron Letters, 2017, 58(20): 1939-1942.
DOI:10.1016/j.tetlet.2017.04.001

摘要

9,10-Dihydro-10-methylacridine (AcrH(2)), a NADH coenzyme model compound, as an organo-photoredox catalyst is demonstrated for the cross-coupling of aryl diazonium salts with (hetero)arenes. Under mild and operationally simple conditions, this new photocatalytic protocol has been applied to arylation of a wide variety of (hetero)arenes and tolerates various functional groups.