An Efficient Biomimetic Aerobic Oxidation of Alcohols Catalyzed by Iron Combined with Amino Acids

作者:Zhang, Guofu; Li, Shasha; Lei, Jie; Zhang, Guihua; Xie, Xiaoqiang; Ding, Chengrong*; Liu, Renhua*
来源:Synlett, 2016, 27(6): 956-960.
DOI:10.1055/s-0035-1561290

摘要

A novel combination of FeCl3, l-valine and TEMPO is found to oxidize alcohols to the carbonyl compounds with dioxygen. A wide range of primary/secondary benzyl, allylic, and heterocyclic alcohols have been efficiently converted into aldehydes and ketones with good to excellent isolated yields.