Alternative Li-Ion Battery Electrode Based on Self-Organized Titania Nanotubes

作者:Ortiz Gregorio F; Hanzu Ilie; Djenizian Thierry*; Lavela Pedro; Tirado Jose L; Knauth Philippe
来源:Chemistry of Materials, 2009, 21(1): 63-67.
DOI:10.1021/cm801670u

摘要

We investigate the fabrication of an alternative electrode for lithium-ion batteries. The active material consists of self-organized TiO(2) nanotube layers prepared by a simple anodization process. The performances of this type of nanostructured electrode are studied by the combination of structural techniques (Scanning electron microscopy and X-ray diffraction) and electrochemical tests. The discharge/charge properties and cycling performance characteristics are studied for both amorphous and crystalline titania nanotubes. With a maximum areal capacity of 77 mu A h cm(-2), a good capacity retention up to 90% over 50 cycles, nanotubular TiO(2) is a promising electrode for rechargeable Li-ion microbatteries.

  • 出版日期2009-1-13