Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-kappa C)nickelate(II) tetrahydrofuran solvate monohydrate

作者：Fang Zhi li^*; Wang Jun

来源：Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1285-U1083.

DOI：10.1107/S1600536810036974

The title complex, [Ni(C(12)H(8)N(2))(2)(H(2)O)(2)][Ni(CN)(4)]center dot C(4)H(8)O center dot H(2)O, consists of a cationic [Ni(C(12)H(8)N(2))(2)(H(2)O)(2)](2+) unit, an anionic [Ni(CN)(4)](2-) unit, one uncoordinated water and one tetrahydrofuran molecule. In the cationic unit, the Ni(2+) atom is coordinated by four N atoms and two O atoms from two 1,10-phenanthroline ligands and two water molecules in a distorted octahedral coordination environment. In the anionic unit, the Ni(2+) atom is in a square-planar coordination by four C atoms from four monodentate terminal cyanide ligands. O-H center dot center dot center dot N and O-H center dot center dot center dot O hydrogen bonds link neighboring cationic and anionic units, forming a three-dimensional supramolecular network. The interstitial tetrahydrofuran molecule is independently disordered over two sites in a 1:1 ratio.

• 出版日期2010-10
• 单位华东交通大学