Scaling the effect of the dipolar interactions on the ZFC/FC curves of random nanoparticle assemblies

作者：Serantes David^*; Pereiro Manuel; Chantrell Roy; Baldomir Daniel

来源：Journal of Magnetism and Magnetic Materials, 2018, 460: 28-33.

DOI：10.1016/j.jmmm.2018.03.026

• Magnetic nanoparticles
• ZFC/FC curves
• Dipolar interactions
• Monte Carlo simulations

Zero field cooling (ZFC) and field cooling (FC) protocols are commonly used to investigate the properties of magnetic nanoparticle systems. For non-interacting conditions the particle properties are fairly well correlated with the shape of the ZFC/FC curves. However, that is not the case when significant dipolar interparticle interactions (DII) are present, which frequently occurs in experimental samples (e.g. aggregates in biological systems; or the dried powder often used for the ZFC/FC measurements). The purpose of this work is to show how the influence of the DII on the ZFC/FC curves, computed by the volume sample concentration c, can be described in a general way if scaled by the dimensionless parameter c(0) = -2K/M-S(2); where K and MS are the anisotropy and saturation magnetization constants of the particles, respectively. This scaling parameter, which is straightforwardly derived from the energy equation governing the system, has an analogous meaning to the normalization of the external magnetic field H by the anisotropy field of the particles HA = 2K/M-S. We use a Monte Carlo technique to illustrate how apparently different T-B vs. c curves of various particles types (where T-B is the blocking temperature), follow the same trend if scaling c/c(0).

• 出版日期2018-8-15