A mixed-ligand dihydrobis(2-mercapto-4-methylthiazolyl) borate) bismuth complex: [Bi(bt(Me))(phen)Cl-2]

作者：Imran Muhammad; Neumann Beate; Mitzel Norbert W^*

来源：Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences, 2015, 70(3): 203-206.

DOI：10.1515/znb-2014-0247

• bismuth
• crystal structure
• mixed-ligand complex
• soft ligand

[Bi(bt(Me))(phen)Cl-2] (bt(Me) = dihydrobis(2-mercapto-4-methylthiazolyl) borate), a mixed-ligand bismuth complex, was prepared from BiCl3, phenanthroline and Na(bt(Me)) and characterized by nuclear magnetic resonance spectroscopy as well as single-crystal X-ray diffraction. It possesses a BiS2N2Cl2 core with distorted octahedral environment constituted by two sulfur atoms of the dipodal boron-centered soft ligand (bt(Me))(-), two nitrogen atoms of the phenanthroline ligand and two chloro ligands.

• 出版日期2015-3