Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of Cu(II) Complex with 2-(1H-1,2,4-triazol-1-yl)acetic Acid

作者：Liu Jia Cheng^*; Cao Jing; Deng Wen Ting

来源：Chinese Journal of Inorganic Chemistry, 2010, 26(2): 343-346.

• copper(II) complex
• hydrothermal synthesis
• crystal structure
• electrochemical property

A copper(II) complex [CuL(2)] [L=2-(1H-1,2,4-triazol-1-yl)acetic acid] has been synthesized by means of hydrothermal method, and characterized by elemental analysis, IR spectra and X-ray diffraction. Crystal data for this complex: monoclinic, space group P2(1)/n, a=0.4813(2) nm, b=1.1511(6) nm, c=0.9939(5) nm, beta=100.528(8)degrees, V=0.5414(5) nm(3) Z=2, F(000)=318, D(c)= 1.937 g center dot cm(-3), Final GooF=1.109, R(1)=0.0276, wR(2)=0.0756. The crystal structure shows the copper(II) atom is six-coordinated by two triazole nitrogen atom and four carboxylate group oxygen atom from four distinct L- ligand, thereby forming a 2D network structure. The cyclic voltammetric behavior of the complex was described. CCDC: 713676.

• 出版日期2010-2-10
• 单位西北师范大学