摘要
Novel electroactive nanostructured silver molybdenum oxyfluoride (SMOF) perovskites Ag(3)(1 )-Mo(6 )(O(3)F(3)) have been successfully synthesized by a mechanochemical reaction. The formation of this perovskite was investigated throughout the Ag-Mo composition range with the use of either Ag(1 ) or Ag(2 ) in the form of AgF and AgF(2) as the reactant, respectively. The compositional study combined with X-ray diffraction and extensive Raman investigation was utilized to determine structure and cation distribution and infer oxidation state. Finally, preliminary electrochemical characterization of the perovskites vs lithium was investigated.
- 出版日期2009-5-26