A palladium complex with functionalized β-cyclodextrin: a promising catalyst featuring recognition abilities for Suzuki-Miyaura coupling reactions in water

作者：Zhang, Guofu^*; Luan, Yuxin; Han, Xingwang; Wang, Yong; Wen, Xin; Ding, Chengrong; Gao, Jianrong

来源：Green Chemistry, 2013, 15(8): 2081-2085.

DOI：10.1039/c3gc40645h

• ARYL CHLORIDES
• NANOPARTICLES
• CHEMISTRY
• LIGAND
• PHARMACEUTICALS
• DERIVATIVES
• OXIDATION
• ALCOHOLS
• ACIDS
• HECK

A water-soluble palladium complex (PdLn@beta-CD) was designed and prepared based on functionalized beta-cyclodextrin. It showed high turnover numbers (TONs) and turnover frequencies (TOFs) of up to 9.9 x 10(8) and 4.9 x 10(8) h(-1), respectively, in aqueous Suzuki-Miyaura coupling reactions. The detailed reason for the excellent catalytic activity was studied.

• 出版日期2013
• 单位浙江工业大学