A 2,2 '-bipyridine coordination complex of [ICl2](+)

作者：Shaw Andrew J M; Corbo Robert; Wilson David J D^*; Dutton Jason L

来源：Dalton Transactions, 2015, 44(34): 15083-15087.

DOI：10.1039/c4dt03549f

The formation of a new class of I(III) compound is reported; an N,N' chelated iodine cation ([bpy-ICl2](+); bpy = 2,2'-bipyridine). The complex is obtained as an [ICl4](-) salt and is formed via simple reaction of bpy with ICl3. The compound is relatively unstable, but may be stored as a solid and is shown to be competent in the oxidative chlorination of Au(I)-NHC complexes.

• 出版日期2015