摘要

Polyurethane (PU) has been rarely used as polymer matrix for preparation of TiO2/polymer hybrids. In this study, PU/nano-TiO2 composite film was prepared by an ultrasonic process through electrostatic interaction. Scanning electron microscopy investigation showed that the PU/nano-TiO2 composite film had a continuous, uniform, and smooth surface. TiO2 nanoparticles were well-dispersed and embedded in the PU matrix. The fluorescence analysis results showed that the film was more sensitive and selective to Pb2+ than to other commonly used metal ions. Similar results were obtained from fluorescence enhancement experiments performed in water. Furthermore, the film exhibited a fast and reversible response to Pb2+ and thus could be used as a sensing film for this ion.

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