A four-coordinate thionitrosyl complex of vanadium

作者：Tran Ba L; Thompson Rick; Ghosh Soumya; Gao Xinfeng; Chen Chun Hsing; Baik Mu Hyun; Mindiola Daniel J^*

来源：Chemical communications, 2013, 49(27): 2768-2770.

DOI：10.1039/c3cc38799b

Addition of elemental sulfur to the vanadium nitride [(nacnac)V N(OAr)] forms the first thionitrosyl complex of vanadium, [(nacnac)V(NS)(OAr)]. Single crystal X-Ray diffraction studies and DFT calculations reveal an almost linear thionitrosyl ligand resulting from an extended pi-resonance across the VNS moiety.

• 出版日期2013