Second-order nonlinear optical properties of Ge-Ga-Ag-S glass irradiated by electron beam

作者：Tao Hai-Zheng^*; Dong Guo-Ping; Xiao Hai-yan; Lin Chang-gui; Zhao Xiu-jian

来源：Transactions of Nonferrous Metals Society of China, 2006, 16: S170-S173.

DOI：10.1016/S1003-6326(06)60168-4

• chalcogenide glasses
• Ge30Ga3Ag4S63
• second-harmonic generation
• microscopic mechanism

Ge-Ga-Ag-S chalcogenide glasses with the composition Ge30Ga3Ag4S63 Were obtained by the conventional melt-quenching method. According to the visible-infrared and infrared spectra, Ge30Ga3Ag4S63 chalcogenide glass possesses wide transmittance window from 510 nm in the visible region up to 11.5 mu m in the infrared region. And the present glass has better glass-forming ability (the difference between glass transition temperature and the peak temperature of crystallization is larger than 100 degrees C). Utilizing maker-fringe technique, a prominent second-harmonic generation was observed in Ge30Ga3Ag4S63 chalcogenide glass after irradiated by an electron beam (Accelerating voltage: 25 kV; Irradiating current: 15 nA; Irradiating time: 10 min). And the mechanism of second-harmonic generation in the Ge-Ga-Ag-S system glasses was discussed.

• 出版日期2006-6
• 单位武汉理工大学